2025

213.Liu,T.;Meng,J.;Qin,H.;Sun,N.;Mei,B.;Li,H.;Zhang,X.-P.*;Li,J.*;Cao,R.*; Mechanistic Studies of Catalytic O2‑to‑H2O2 Conversion at a Single Cobalt Site. J. Am. Chem. Soc., 2025, 47, 26, 22322−22328.

212.Chen,Y.;Yang,S.;Wang,T.;Li,S.;Liu,X.;Zhang,W.*;Cao,R.*; Mo-Doped α-MnO2 for Enhanced Electrocatalytic Water Oxidation. ChemSusChem, 2025, 18, e202401553.

211.Li,C.-G.;Mo,L.-M.;Wei,D.-D.;Duan,H.-M.;Thapper,A.;Zhao,J.;Chen,J.-T.;Zhang,L.*;Hu,Z.-F.*Wang,H.-Y.*; Advancing Photocatalytic Diels−Alder Conversion of Biomassderived Compounds on Red Phosphorus via C−H Activation. ACS Catal., 2025, 15, 11074−11081.

210.Duan,H.-M.;Li,C.-G.;Mo,L.-M.;Thapper,A.*;Wang,H.-Y.*; Unassisted Switchable Dual-Photoelectrode Devices Utilizing p-n Carbon Quantum Dots as "Semiconductor Electrolytes": Optimization Between H2O2 and Solar Elec. Adv. Sci., 2025, 12, e17204.

209.Bai,B.;Pan,Y.;Zhao,J.;Zhang,X.-P.*;Cao,R.; Origins of HCOOH Selectivity Over CO Mediated by an Unusual Fe(I)- Porphyrin Bearing a β‑Substituted Cation. Inorg. Chem., 2025, 64, 4826−4834.

208.Lei,H.;Li,F.;Liu,C.;Li,J.;Wang,Y.;Nam,D.-H.;Lum,Y.;Guo,S.-X.;Lai,W.*;Cao,R.*; Highly selective electrocatalytic CO2 reduction to formate by a dinuclear nickel complex: cooperative catalysis across diverse conditions. Sci. Bull., 2025, 70, 4005–4013.
207.Lei,H.*;Han,J.;Zhao,Q.;Liu,J.;Yan,L.;Zhang,W.*;Cao,R.*; Metalloporphyrin- and metallocorrole-based catalysts for the oxygen reduction reaction: from molecules to materials. Chem. Soc. Rev., 2025, 54, 11488–11544.

206.Liu,S.;Cao,Y.;Liang,Z.*;Cao,R.*; Co4(SO4)4 Cluster-Based Metal Porphyrin Frameworks Derived CoM-NSC Materials for Efficient Oxygen Electrocatalysis. ChemCatChem, 2025, 17, e01095.

205.Han,A.;Fang,P.;Zhao,Q.;Zhao,J.;Yin,J.;Lei,H.*;Cao,R.*; Co phthalocyanine covalent organic frameworks with enhanced p-electron delocalization for boosted electrocatalytic CO2 reduction reaction. Chem. Commun., 2025, 61, 16624.

204.He,H.;Jian,Y.;Liu,J.*;Yin,Z.;Lu,Q.;Lei,H.*;Zhang,W.;Cao,R.*; Doubly Urea-Bridged Face-to-Face Dinuclear Metalloporphyrins for Efficient Electrocatalytic CO2 Reduction in Aqueous Solutions. ChemSusChem, 2025, 18, e202501485.

203.Song,L.;Liu,Y.;Wang,J.;Wu,R.;Zhang,W.;Cao,R.;Dang,J.*;Zheng,H.*; Hierarchically porous two-dimensional Fe/Ncodoped carbon nanoleaves for enhanced mass transfer and electrocatalytic oxygen reduction reaction. Energy Mater., 2025, 5, 500139.

202.Wang,T.;Pei,Z.;Chen,D.;Yang,S.;Liu,X.;Cao,R.;Zhang,X.-P.*;Zhao,J.*;Zhang,W.*; Single Crystalline CoNi Selenite for Investigating a Metal Synergic Effect in Electrocatalytic Water Oxidation. ACS Catal., 2025, 15, 13, 11519–11529.

201.Cao,Y.;Zhang,J.;Han,J.;Li,G.;Ma,W.;Zheng,H.;Liang,Z.*;Cao,R.*; Porous Co@NC Materials Obtained by Pyrolyzing Metal-Organic Framework-Supported Multinuclear Metal Clusters for the Oxygen Reduction Reaction. Chem. Eur. J., 2025, 31, e202501464.

200.Ma,Y.;Hua,R.;Pan,Y.;Li,X.;Ma,M.;Wang,M.;Ding,H.;Zheng,H.*; Highly dispersed Pt anchored on hollow carbon nanobowls: negative curvature enhances electrocatalytic hydrogen evolution. Chem. Commun., 2025, 61, 9318-9321.

199.Zhang,J.;Liang,Z.*;Li,Z.;Qu,S.;Cao,Y.;Zheng,H.;Cao,R.*; Recent progress in curved materials for oxygen electrocatalysis. Sustain. Energy Fuels, 2025, 9, 3152.

198.Liang,Z.*;Lei,H.;Zheng,H.;Zhang,W.;Wang,H.;Cao,R.*; Selective two-electron and four-electron oxygen reduction reactions using Co-based electrocatalysts. Chem. Soc. Rev., 2025, 54, 5248–5291.

197.Yin,Z.;Zhang,M.;Long,Y.;Lei,H.;Li,X.;Zhang,X.-P.*;Zhang,W.;Apfel,U.;Cao,R.*; Improving Electrocatalytic CO2 Reduction over Iron Tetraphenylporphyrin with Triethanolamine as a CO2 Shuttle. Angew. Chem. Int. Ed., 2025, 64, e202500154.

196.Mou,Y.;Zhang,J.;Qin,H.;Li,X.;Zeng,Z.;Zhang,R.;Liang,Z.*;Cao,R.*; The steric hindrance effect of Co porphyrins promoting two-electron oxygen reduction reaction selectivity. Chem. Commun., 2025, 61, 1878-1881.

194.Ma,M.;Pei,Z.;Peng,Y.;Hua,R.;Ma,Y.;Wang,W.;Xu,X.*;Zhang,X.*;Zheng,H.*; Single Zn atoms anchored in mesoporous N-doped carbon rods derived from metal–organic frameworks for enhanced electrocatalytic oxygen reduction reaction. J. Mater. Chem. A, 2025, 13, 7529-7538.

194.Zhang,J.;Han,Y.;Cao,Y.;Xu,Y.;Wang,M.;Wang,Y.*;Zheng,H.*;Cao,R.*;Liang,Z.*; Co nanoparticles encapsulated in N-doped carbon nanotube materials derived from new metal–organic frameworks for oxygen electrocatalysis. J. Mater. Chem. A, 2025, 13, 669-679.

193.Zhang,J.;Mou,Y.;Suo,W.;Yang,S.;Shen,J.;Xu,H.;Zeng,Z.;Zhang,R.;Liang,Z.*;Wang,Y.*;Zheng,H.*;Cao,J.*;Cao,R.*; Single-Atomic Co-N-C Sites Anchored on Helical Carbonaceous Nanotubes for the Oxygen Reduction Reaction. Adv. Funct. Mater., 2025, 35, 2417621.

192.Qin,H.;Kong,J.;Peng,X.;Wang,Z.;Li,X.;Lei,H.;Zhang,W.;Cao,R.*; Revealing Significant Electronic Effects on the Oxygen Reduction Reaction with Iron Porphyrins. ChemSusChem, 2025, 18, 3, e202401739.
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